A trio will become one very stressed Discus given time. With just three, there won't be enough fish to spread the agression, and thus the weakest in the group will be bullied to death by the other two once settled. After the first death, the other two will turn on each other and history will repeate

The time it takes for this to happen will depend on the individual fish, but sooner or later you would come home to a bloodbath, unless the two remaining fish were a compatible pair

The minumum number for duscus would either be 5, or a proven breeding pair

This spreads the agression in the case of a group, and breeding pairs show no agression amongst themselves
Discus are shoaling fish, so one alone will feel insecure and stressed. This lone fish may then refuse to eat and die a few months later of starvation. Discus are amongst a select few fish that are happy to starve to death if something isn't right.
Though not out-and-out agressive, you must remember that Discus are Cichlids and thus are considered semi-agressive. My current dominant discus has a very nasty side to him/her, as it will be more interested in tareing chunks out of the other fish, than acctually eating the food

Agression is usually kept within the group though, with the fish showing a clear hirachy in a tank into which they have settled
Your tank needs to be 50g minimum with very good filtration (preferably on two exturnals each capable of filtering the tank alone) and a minimum height of 18 inches. I'd advise you to cycle the tank fishlessly (using liquid ammonia), and mature it first for about 6 months with other fish before introducing your discus.
In answer to your origional question though, no discus won't eat smaller fish like neons, so long as the small fish are fully grown once they are past about 4 inches. Like any fish, if it fits in their mouth, they will try to fit it in
If after reading that, you are still interested, post back with any queries. A trio isn't doable (not easily at least, especially not in a small tank under 100g) so you will need at least 5 to start out
The key to Discus is research. If you want to keep them, read any keeping information you can get your hands on and learn it untill you can answer any Discus question correctly, before buying your stock. Once you are ready for your stock, forget the research and copy someone elses (already working) set-up. If the copied set-up doesn't work, tweak on the gut instinct that you should get from your research.
If it works, don't fix it
All the best
Rabbut