Yes you should do a big water change around 80% before you go out and get the fish. Also do the water change as close as you can to getting the fish, either the morning you are going to get them, or the night before.
As previous poster said, make sure that your tank is processing everything quickly enough, and don't rush out to get fish just because you see that your nitrites are now at 0.
Edit: oh dear, i've just seen your newest post. You should definitely go out and buy a liquid test kit before buying any fish, as you have no idea whether or not your tank i scycled.