The nitrogen in liquid form we add is as KNO3, which I think makes it more available to the plants, nitrogen in pure gas form probably isn't available to the plants. In the terrestrial environment, nitrifying bacteria in the soil convert nitrogen gas to a form plants can use, would think the same would be required in the planted tank, which it probably wont be, so it might be a waste of time. That said give it a go! Does sounds a bit pointless though, adding KNO3 in powered or liquid form is so easy, why make it more complicated?
Sam