I can't really say anything that hasn't been said, but I can stretch it out a bit ...
Basically, you probably shouldn't add livebearers. Gouramis can, and usually are aggressive fish (Granted, not the MOST aggressive, but none-the-less), and livebearers like guppies wouldn't be so well suited to the environment.
Mollies could be a different issue altogether, depending on the type. Mollies generally prefer a brackish environment, and that's only if they don't require it in the first place. Size would also be an issue, with some mollies getting fairly large. Though this would better serve them against the gouramis' aggressive tendencies, it would limit the number you could have greatly, and the tank does seem somewhat full already.
Swords could go either way. They're generally hardy, though a male will get rather possessive over any females around, and could end up turning on the smaller fish in the tank. Again, these ones can get somewhat large, so the number would be limited.
Platies are generally well natured, but like guppies, they're smallish in a larger environment. They're faster though, so ... Yeah, it could help out, but stress was the concern here from the beginning.
Ultimately, the point stands that you probably shouldn't add anything to the tank, for the reasons that it's well stocked already, and the fish you'd add may not fare so well. It would, quite simply, be a better option to raise the barb count before adding another species entirely.
Hope this elaborates and helps some.