drip some vinegar on them if they don't fizz they should be ok just make sure u give em a good scrub, some people bake em or boil em but i can see the oven exploding if i tried that with rocks so wouldn't recommend it.
boil them a couple of times to get rid of any nasties etc, let them cool, add vinegar as stated above. if the vinegar doesnt fizz then they are ok to add to your tank