I read that if you wanted to get the 2 readings, you take it in the morning and at night.
So just before lights go on, and just before lights go off. I imagine that would give the 2 extremes. I only really test in evening now. But when I was first testing when I first added CO2 my pH would be 6.4 to 6.7 Cant remember which was evening and which was morning tho.